Tf is the freezing point of the solution(the solvent plus solute).
T*f is the freezing point of the pure solvent(without solute)
i is the van't Hoff factor.It is approximately the number of particles in solution that are made for each particle of the solute that is placed into solution.Therefore, for nonelectrolytes, i = 1.
Kf is the freezing point depression constant.For water, Kf = 1.86 Degree C/m, or 1.86 Degree C.kg/mol.
Tf is -1.58 Degree C
